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KMID : 1024520150240010001
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Journal of the Environmental Sciences
2015 Volume.24 No. 1 p.1 ~ p.7
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Preparation of Solid-Phase Extractant by Immobilizing Di-(2-ethylhexyl)phosphoric Acid (D2EHPA) and Tri-butyl-phosphate (TBP) in Polysulfone and Removal Characteristics of Cu(II)
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Kam Sang-Kyu
Jeon Jin-Wo
Lee Min-Gyu
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Abstract
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The solid-phase extractant PS-D2EHPA/TBP was prepared by immobilizing two extractants D2EHPA and TBP in polysulfone (PS). The prepared PS-D2EHPA/TBP was characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal of Cu(II) from aqueous solution was investigated in batch system. The experiment data were obeyed the pseudo-second-order kinetic model. Equilibrium data were well fitted by Langmuir model and the removal capacity of Cu(II) by solid extractant PS-D2EHPA/TBP obtained from Langmuir model was 3.11 mg/g at 288 K. The removal capacity of Cu(II) was increased according to increasing pH from 2 to 6, but the removal capacity was decreased below pH 3 remarkably.
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KEYWORD
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Copper, Solid-phase extractant, Di-(2-ethylhexyl) phosphoric acid (D2EHPA), Tri-butyl-phosphate (TBP), Immobilization, Polysulfone (PS)
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